Trapping five-coordinate platinum(iv) intermediates

Trapping five-coordinate platinum(iv) intermediates.

The oxidation of three different complexes of the doubly cycloplatinated 2,6-di(4-fluorophenyl)pyridine ligand (namely DMSO, PPh3 and PPr3 derivatives, 1a, 1b and 1c, respectively) with the electrophilic oxidant iodobenzenedichloride was studied. In each case oxidation can yield a simple trans-dichloro platinum(iv) complex (2(t)), which subsequently isomerises to the cis isomer (2(c)). However,...

True and masked three-coordinate T-shaped platinum(II) intermediates

Although four-coordinate square-planar geometries, with a formally 16-electron counting, are absolutely dominant in isolated Pt(II) complexes, three-coordinate, 14-electron Pt(II) complexes are believed to be key intermediates in a number of platinum-mediated organometallic transformations. Although very few authenticated three-coordinate Pt(II) complexes have been characterized, a much larger ...

Trapping Enyzme Reaction Intermediates by Freeze-Quench XAS

Highly enantioselective trapping of zwitterionic intermediates by imines.

Reactions with the unstable and highly reactive zwitterionic intermediates generated in processes catalysed by transition metals are providing new opportunities for molecular constructions. Insertion reactions involve the collapse of zwitterionic intermediates, but trapping them would allow structural elaborations that are not currently available. To synthesize complex molecules in this manner,...

Kink-antikink, trapping bags and five-dimensional Gauss-Bonnet gravity

Five-dimensional Gauss-Bonnet gravity, with one warped extra-dimension, allows classes of solutions where two scalar fields combine either in a kink-antikink system or in a trapping-bag configuration. While the kink-antikink system can be interpreted as a pair of gravitating domain walls with opposite topological charges, the trapping-bag solution consists of a domain wall supplemented by a non...